A simple experiment involving rust...

Let's take a look at the common, everyday occurance of rust. We see rust, that reddish-brown flaky stuff, on the sides of old cars, or on our bicycle that we absent-mindedly left outside for an entire winter. But what is rust caused by? You can try this simple experiment at home to find out.

What you need:

Two pieces of steel wool

Two pie pans

Two glass cups or beakers

Some water

Two pieces of clay or putty

What you do:

Fill the pie pan with water until it is half full. Stick the putty to one side of the steel wool, and attach the steel wool to the bottom of the glass. Place the glass, upside down, into the pie pan. Leave this to sit overnight and observe any changes during the next few days. Repeat the same procedure with the second set of materials, only this time, fill the pie pan with more water. Let the second set sit overnight as well.

 

What's going on here?

If all goes right, the water should begin to rise up into the glass and the steel wool should start to rust. Why does this happen? Well, rust forms as the steel, which is mainly composed of iron, reacts with the oxygen in the air. But if I left a piece of steel wool on the countertop overnight, it would not rust. The key is that we are suspending the iron over water. Inside the tube, there are the correct elements for rust: iron, oxygen in the air, and water vapor. How do I know that there is water vapor in the glass? Any time we have liquid water, a certain amount of that liquid spontaneously turns to gas even if we didn't heat it! The oxygen combines with regular iron to turn it into iron(III) oxide. Iron (III) oxide, Fe2 O3, is commonly known as rust.

So, why does the water rise up in the glass? Because oxygen gas is being consumed in the reaction, there are less oxygen particles in the glass. If there are less particles of oxygen, fewer particles hit the sides of the glass as they move around. This decreases the pressure inside the glass. How do we know this? Click here for a small discussion of pressure. If the pressure on the inside of the glass is lower than the pressure of the air that is pushing down on the water in the pie pan, the air outside pushes the water up and into the glass to equalize the pressure. Click here for a discussion of equilibrium.
What does this tell us about how fast the oxygen reacts with the iron? Did the water level of the two separate sets differ? If not, we know that a certain size of steel wool and a certain size of beaker will give similar results. So, we could predict how fast the reaction will proceed by knowing the level the water should be at when the reaction is finished. To test this, use a piece of tape or putty to mark the line where the water ended up on the finished experiment. You can then repeat the experiment, checking every hour during the day, and find out how long it took for the water level to rise to the tape. This would tell you how fast the oxygen reacted with the steel wool.

Notes for the teacher:

Leave a piece of steel wool in a beaker filled with water, completely submerged overnight while the students are leaving their experiments. Next to the beaker, leave a dry piece of steel wool. Ask the students why neither of the two that you prepared rusted, when all of their steel wool did. This should lead the students down the road to the triad of water, oxygen, and iron.


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